If you want to add music files like MP3s from your PC to iTunes, the basic operation is "Add File to Library." For multiple songs, you can add them by folder. First, try importing them without moving ...
ACL found but not expected on "Library/iTunes". Repaired "Library/iTunes". If I run Repair Permissions again, I get the same log. So clearly it's not being fixed. And the core symptom (can't sync) ...