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A tri-bismuth(i) equivalent of the allyl cation (🔎 https://ccdc-info.com/3DQG13l) is reported in Nature Chemistry. This complex represents the periodic table's heaviest and stable π-allyl cation and acts as a source of low-valent bismuth complexes through Bi(i) transfer. 🔗 CSD Entry HUFKIG: https://ccdc-info.com/4hAvhoD #FeaturedStructureFriday #Crystallography | Cambridge Crystallographic Data Centre (CCDC)
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